{"id":404029,"date":"2026-03-26T00:45:11","date_gmt":"2026-03-26T00:45:11","guid":{"rendered":"https:\/\/www.europesays.com\/ie\/404029\/"},"modified":"2026-03-26T00:45:11","modified_gmt":"2026-03-26T00:45:11","slug":"electrochemical-corrosion-accompanies-dendrite-growth-in-solid-electrolytes","status":"publish","type":"post","link":"https:\/\/www.europesays.com\/ie\/404029\/","title":{"rendered":"Electrochemical corrosion accompanies dendrite growth in solid electrolytes"},"content":{"rendered":"
  • \n

    Sudworth, J. L., Hames, M. D., Storey, M. A., Azim, M. F. & Tilley, A. R. An analysis and laboratory assessment of two sodium sulfur cell designs. Power Sources 4<\/b>, 1\u201318 (1972).<\/p>\n


    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Sharafi, A., Meyer, H. M., Nanda, J., Wolfenstine, J. & Sakamoto, J. Characterizing the Li\u2013Li7La3Zr2O12 interface stability and kinetics as a function of temperature and current density. J. Power Sources 302<\/b>, 135\u2013139 (2016).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Armstrong, R. D., Dickinson, T. & Turner, J. The breakdown of \u03b2-alumina ceramic electrolyte. Electrochim. Acta 19<\/b>, 187\u2013192 (1974).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Athanasiou, C. E. et al. Operando measurements of dendrite-induced stresses in ceramic electrolytes using photoelasticity. Matter 7<\/b>, 95\u2013106 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhu, Y., He, X. & Mo, Y. Origin of outstanding stability in the lithium solid electrolyte materials: insights from thermodynamic analyses based on first-principles calculations. ACS Appl. Mater. Interfaces 7<\/b>, 23685\u201323693 (2015).<\/p>\n

    Article<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Ma, C. et al. Interfacial stability of Li metal\u2013solid electrolyte elucidated via in situ electron microscopy. Nano Lett. 16<\/b>, 7030\u20137036 (2016).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Connell, J. G. et al. Kinetic versus thermodynamic stability of LLZO in contact with lithium metal. Chem. Mater. 32<\/b>, 10207\u201310215 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Porz, L. et al. Mechanism of lithium metal penetration through inorganic solid electrolytes. Adv. Energy Mater. 7<\/b>, 1701003 (2017).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Ning, Z. et al. Dendrite initiation and propagation in lithium metal solid-state batteries. Nature 618<\/b>, 287\u2013293 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Fincher, C. D. et al. Controlling dendrite propagation in solid-state batteries with engineered stress. Joule 6<\/b>, 2794\u20132809 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    McConohy, G. et al. Mechanical regulation of lithium intrusion probability in garnet solid electrolytes. Nat. Energy 8<\/b>, 241\u2013250 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Klinsmann, M., Hildebrand, F. E., Ganser, M. & McMeeking, R. M. Dendritic cracking in solid electrolytes driven by lithium insertion. J. Power Sources 442<\/b>, 227226 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Mukherjee, D. et al. Ingress of Li into solid electrolytes: cracking and sparsely filled cracks. Small Struct. 4<\/b>, 2300022 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Qi, Y., Ban, C. & Harris, S. J. A new general paradigm for understanding and preventing Li metal penetration through solid electrolytes. Joule 4<\/b>, 2599\u20132608 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Brewster, D. X. On the communication of the structure of doubly refracting crystals to glass, muriate of soda, fluor spar, and other substances, by mechanical compression and dilatation. By David Brewster, LL. DFRS Lond. and Edin. In a letter addressed to the Right Hon. Sir Joseph Banks, Bart. GCBPR S. Philos. Trans. R. Soc. Lond. 156\u2013178 (1816).<\/p>\n<\/li>\n

  • \n

    Sneddon, I. N. The distribution of stress in the neighbourhood of a crack in an elastic solid. Proc. R. Soc. Lond. A Math. Phys. Sci. 187<\/b>, 229\u2013260 (1946).<\/p>\n

    ADS<\/a>\u00a0
    \n     MathSciNet<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Anstis, G. R., Chantikul, P., Lawn, B. R. & Marshall, D. B. A critical evaluation of indentation techniques for measuring fracture toughness: I, direct crack measurements. J. Am. Ceram. Soc. 64<\/b>, 533\u2013538 (1981).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Hao, S. et al. Tracking lithium penetration in solid electrolytes in 3D by in-situ synchrotron X-ray computed tomography. Nano Energy 82<\/b>, 105744 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Gao, H. et al. Visualizing the failure of solid electrolyte under GPa-level interface stress induced by lithium eruption. Nat. Commun. 13<\/b>, 5050 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     PubMed Central<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Hao, S. et al. 3D imaging of lithium protrusions in solid-state lithium batteries using X-ray computed tomography. Adv. Funct. Mater. 31<\/b>, 2007564 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Kazyak, E. et al. Li penetration in ceramic solid electrolytes: operando microscopy analysis of morphology, propagation, and reversibility. Matter 2<\/b>, 1025\u20131048 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Kinzer, B. et al. Operando analysis of the molten Li|LLZO interface: understanding how the physical properties of Li affect the critical current density. Matter 4<\/b>, 1947\u20131961 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Reisecker, V. et al. Effect of pulse-current-based protocols on the lithium dendrite formation and evolution in all-solid-state batteries. Nat. Commun. 14<\/b>, 2432 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     PubMed Central<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhang, Y. et al. Mechanical origin of lithium dendrite penetration in garnet solid electrolyte. Preprint at https:\/\/chemrxiv.org\/doi\/full\/10.26434\/chemrxiv-2025-frphl<\/a> (2025).<\/p>\n<\/li>\n

  • \n

    Zhao, J. et al. In situ observation of Li deposition-induced cracking in garnet solid electrolytes. Energy Environ. Mater. 5<\/b>, 524\u2013532 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhu, Y. et al. Dopant-dependent stability of garnet solid electrolyte interfaces with lithium metal. Adv. Energy Mater. 9<\/b>, 1803440 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Schwietert, T. K., Vasileiadis, A. & Wagemaker, M. First-principles prediction of the electrochemical stability and reaction mechanisms of solid-state electrolytes. JACS Au 1<\/b>, 1488\u20131496 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     PubMed Central<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Miara, L. J. et al. Effect of Rb and Ta doping on the ionic conductivity and stability of the garnet Li7+2x\u2013y(La3\u2013xRbx)(Zr2\u2013yTay)O12 (0 \u2264 x \u2264 0.375, 0 \u2264 y \u2264 1) superionic conductor: a first principles investigation. Chem. Mater. 25<\/b>, 3048\u20133055 (2013).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Xiao, Y. et al. Understanding interface stability in solid-state batteries. Nat. Rev. Mater. 5<\/b>, 105\u2013126 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Chang, W. et al. Evolving contact mechanics and microstructure formation dynamics of the lithium metal-Li7La3Zr2O12 interface. Nat. Commun. 12<\/b>, 6369 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     PubMed Central<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Jain, A. et al. Commentary: The Materials Project: a materials genome approach to accelerating materials innovation. APL Mater. 1<\/b>, 011002 (2013).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zagorac, D., M\u00fcller, H., Ruehl, S., Zagorac, J. & Rehme, S. Recent developments in the Inorganic Crystal Structure Database: theoretical crystal structure data and related features. Appl. Crystallogr. 52<\/b>, 918\u2013925 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Hayashi, K., Noguchi, H. & Fujiwara, S. New phases In La2O3\u2013Li2O\u2013Ta2O5 system. Mater. Res. Bull. 21<\/b>, 289\u2013293 (1986).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zocchi, M., Sora, I. N., Depero, L. E. & Roth, R. S. A single-crystal X-ray diffraction study of lithium zirconate, Li6Zr2O7, a solid-state ionic conductor. J. Solid State Chem. 104<\/b>, 391\u2013396 (1993).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Hamao, N., Kataoka, K., Kijima, N. & Akimoto, J. Synthesis, crystal structure and conductive properties of garnet-type lithium ion conductor Al-free Li7\u2212xLa3Zr2\u2212xTaxO12 (0 \u2264 x \u2264 0.6). J. Ceram. Soc. Jpn. 124<\/b>, 678\u2013683 (2016).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Peng, X. et al. Unraveling Li growth kinetics in solid electrolytes due to electron beam charging. Sci. Adv. 9<\/b>, eabq3285 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     PubMed Central<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Reimer, L. & Kohl, H. Transmission Electron Microscopy: Physics of Image Formation (Springer, 2008).<\/p>\n<\/li>\n

  • \n

    Garvie, R. C., Hannink, R. H. & Pascoe, R. T. Ceramic steel? Nature 258<\/b>, 703\u2013704 (1975).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    McMeeking, R. M. & Evans, A. G. Mechanics of transformation-toughening in brittle materials. J. Am. Ceram. Soc. 65<\/b>, 242\u2013246 (1982).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Evans, A. G. & Cannon, R. M. Toughening of brittle solids by martensitic transformations. Acta Metall. 34<\/b>, 761\u2013800 (1986).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Xu, C., Ahmad, Z., Aryanfar, A., Viswanathan, V. & Greer, J. R. Enhanced strength and temperature dependence of mechanical properties of Li at small scales and its implications for Li metal anodes. Proc. Natl Acad. Sci. 114<\/b>, 57\u201361 (2017).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Herbert, E. G., Dudney, N. J., Rochow, M., Thole, V. & Hackney, S. A. On the mechanisms of stress relaxation and intensification at the lithium\/solid-state electrolyte interface. J. Mater. Res. 34<\/b>, 3593\u20133616 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Fincher, C. D., Ojeda, D., Zhang, Y., Pharr, G. M. & Pharr, M. Mechanical properties of metallic lithium: from nano to bulk scales. Acta Mater. 186<\/b>, 215\u2013222 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Stallard, J. C., Vema, S., Grey, C. P., Deshpande, V. S. & Fleck, N. A. The strength of a constrained lithium layer. Acta Mater. 260<\/b>, 119313 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Park, R. J.-Y. et al. Semi-solid alkali metal electrodes enabling high critical current densities in solid electrolyte batteries. Nat. Energy 6<\/b>, 314\u2013322 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Sandoval, S. E. et al. Electro-chemo-mechanics of anode-free solid-state batteries. Nat. Mater. 24<\/b>, 673\u2013681 (2025).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Thompson, T. et al. Electrochemical window of the Li-ion solid electrolyte Li7La3Zr2O12. ACS Energy Lett. 2<\/b>, 462\u2013468 (2017).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Doux, J.-M. et al. Stack pressure considerations for room-temperature all-solid-state lithium metal batteries. Adv. Energy Mater. 10<\/b>, 1903253 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Schwietert, T. K. et al. Clarifying the relationship between redox activity and electrochemical stability in solid electrolytes. Nat. Mater. 19<\/b>, 428\u2013435 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Shribak, M. & Oldenbourg, R. Techniques for fast and sensitive measurements of two-dimensional birefringence distributions. Appl. Opt. 42<\/b>, 3009\u20133017 (2003).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n","protected":false},"excerpt":{"rendered":"Sudworth, J. L., Hames, M. D., Storey, M. A., Azim, M. F. & Tilley, A. R. An analysis…\n","protected":false},"author":2,"featured_media":404030,"comment_status":"","ping_status":"","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[77],"tags":[58265,18,1099,19,17,1100,133],"class_list":{"0":"post-404029","1":"post","2":"type-post","3":"status-publish","4":"format-standard","5":"has-post-thumbnail","7":"category-science","8":"tag-batteries","9":"tag-eire","10":"tag-humanities-and-social-sciences","11":"tag-ie","12":"tag-ireland","13":"tag-multidisciplinary","14":"tag-science"},"share_on_mastodon":{"url":"","error":""},"_links":{"self":[{"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/posts\/404029","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/comments?post=404029"}],"version-history":[{"count":0,"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/posts\/404029\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/media\/404030"}],"wp:attachment":[{"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/media?parent=404029"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/categories?post=404029"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/tags?post=404029"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}