{"id":545280,"date":"2026-06-20T14:02:17","date_gmt":"2026-06-20T14:02:17","guid":{"rendered":"https:\/\/www.europesays.com\/ie\/545280\/"},"modified":"2026-06-20T14:02:17","modified_gmt":"2026-06-20T14:02:17","slug":"structural-origin-of-line-tension-reversal-in-nanoscale-wetting-of-water","status":"publish","type":"post","link":"https:\/\/www.europesays.com\/ie\/545280\/","title":{"rendered":"Structural origin of line-tension reversal in nanoscale wetting of water"},"content":{"rendered":"
  • \n

    Bonn, D., Eggers, J., Indekeu, J., Meunier, J. & Rolley, E. Wetting and spreading. Rev. Mod. Phys. 81<\/b>, 739 (2009).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Bjorneholm, O. et al. Water at interfaces. Chem. Rev. 116<\/b>, 7698\u20137726 (2016).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Indekeu, J. Line tension at wetting. Int. J. Mod. Phys. B 8<\/b>, 309\u2013345 (1994).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Kaiser, N., Croell, A., Szofran, F., Cobb, S. D. & Benz, K. W. Wetting angle and surface tension of germanium melts on different substrate materials. J. Cryst. Growth 231<\/b>, 448\u2013457 (2001).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Yuan, Z., Huang, W. L. & Mukai, K. Wettability and reactivity of molten silicon with various substrates. Appl. Phys. A 78<\/b>, 617\u2013622 (2004).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Drevet, B. & Eustathopoulos, N. Wetting of ceramics by molten silicon and silicon alloys: a review. J. Mater. Sci. 47<\/b>, 8247\u20138260 (2012).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Tanaka, H. Simple view of waterlike anomalies of atomic liquids with directional bonding. Phys Rev. B 66<\/b>, 064202 (2002).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Young, T. III. An essay on the cohesion of fluids. Philos. Trans. R. Soc. Lond. 95<\/b>, 65\u201387 (1805).<\/p>\n

    ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Gibbs, J. W. Scientific Papers of J. Willard Gibbs: Thermodynamics Vol. 1 (Longmans, Green and Company, 1906).<\/p>\n<\/li>\n

  • \n

    Boruvka, L. & Neumann, A. Generalization of the classical theory of capillarity. J. Chem. Phys. 66<\/b>, 5464\u20135476 (1977).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Kandu\u010d, M., Eixeres, L., Liese, S. & Netz, R. R. Generalized line tension of water nanodroplets. Phys. Rev. E 98<\/b>, 032804 (2018).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Shintaku, M. et al. Measuring line tension: thermodynamic integration during detachment of a molecular dynamics droplet. J. Chem. Phys. 160<\/b>, 224502 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhao, B. et al. Resolving the apparent line tension of sessile droplets and understanding its sign change at a critical wetting angle. Phys. Rev. Lett. 123<\/b>, 094501 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Clarke, A. S. Thermal fluctuations of a three phase contact line. I. Two fluid phases and one solid phase. J. Chem. Phys. 96<\/b>, 9073\u20139077 (1992).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Clarke, A. S. Thermal fluctuations of a three phase contact line. II. Three fluid phases. J. Chem. Phys. 96<\/b>, 9078\u20139082 (1992).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Law, B. M. et al. Line tension and its influence on droplets and particles at surfaces. Prog. Surf. Sci. 92<\/b>, 1\u201339 (2017).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    De Gennes, P.-G. Wetting: statics and dynamics. Rev. Mod. Phys. 57<\/b>, 827 (1985).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     MathSciNet<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Granick, S. Motions and relaxations of confined liquids. Science 253<\/b>, 1374\u20131379 (1991).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Scatena, L. F., Brown, M. G. & Richmond, G. L. Water at hydrophobic surfaces: weak hydrogen bonding and strong orientation effects. Science 292<\/b>, 908\u2013912 (2001).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Shen, Y. R. & Ostroverkhov, V. Sum-frequency vibrational spectroscopy on water interfaces: polar orientation of water molecules at interfaces. Chem. Rev. 106<\/b>, 1140\u20131154 (2006).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Nihonyanagi, S., Yamaguchi, S. & Tahara, T. Direct evidence for orientational flip-flop of water molecules at charged interfaces: a heterodyne-detected vibrational sum frequency generation study. J. Chem. Phys. 130<\/b>, 204704 (2009).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Shen, Y. Phase-sensitive sum-frequency spectroscopy. Annu. Rev. Phys. Chem. 64<\/b>, 129\u2013150 (2013).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Urashima, S., Myalitsin, A., Nihonyanagi, S. & Tahara, T. The topmost water structure at a charged silica\/aqueous interface revealed by heterodyne-detected vibrational sum frequency generation spectroscopy. J. Phys. Chem. Lett. 9<\/b>, 4109\u20134114 (2018).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Wang, Y. et al. Spontaneous surface charging and janus nature of the hexagonal boron nitride\u2013water interface. J. Am. Chem. Soc. 147<\/b>, 30107\u201330116 (2025).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Wang, Y., Litman, Y., Cho, M., Cox, S. & Bonn, M. Wetting transparency of graphene: a macroscopic window but nanoscopic mirror. Preprint at https:\/\/arxiv.org\/abs\/2511.04930<\/a> (2025).<\/p>\n<\/li>\n

  • \n

    Wang, Y. et al. Interfaces govern the structure of angstrom-scale confined water solutions. Nat. Commun. 16<\/b>, 7288 (2025).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Johansson, P. & Hess, B. Molecular origin of contact-line friction in dynamic wetting. Phys. Rev. Fluids 3<\/b>, 074201 (2018).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Blake, T. D. & De Coninck, J. The influence of solid\u2013liquid interactions on dynamic wetting. Adv. Colloid Interface Sci. 96<\/b>, 21\u201336 (2002).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Fan, J., De Coninck, J., Wu, H. & Wang, F. Microscopic origin of capillary force balance at contact line. Phys. Rev. Lett. 124<\/b>, 125502 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhu, C., Li, H., Huang, Y., Zeng, X. C. & Meng, S. Microscopic insight into surface wetting: relations between interfacial water structure and the underlying lattice constant. Phys. Rev. Lett. 110<\/b>, 126101 (2013).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Taherian, F., Leroy, F., Heim, L.-O., Bonaccurso, E. & van der Vegt, N. F. A. Mechanism for asymmetric nanoscale electrowetting of an ionic liquid on graphene. Langmuir 32<\/b>, 140\u2013150 (2016).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Molinero, V. & Moore, E. B. Water modeled as an intermediate element between carbon and silicon. J. Phys. Chem. B 113<\/b>, 4008\u20134016 (2009).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Sbarra, S., Waquier, L., Suffit, S., Lema\u00eetre, A. & Favero, I. Optomechanical measurement of single nanodroplet evaporation with millisecond time-resolution. Nat. Commun. 13<\/b>, 6462 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Cao, P., Xu, K., Varghese, J. O. & Heath, J. R. The microscopic structure of adsorbed water on hydrophobic surfaces under ambient conditions. Nano Lett. 11<\/b>, 5581\u20135586 (2011).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Song, J. et al. Evidence of Stranski\u2013Krastanov growth at the initial stage of atmospheric water condensation. Nat. Commun. 5<\/b>, 4837 (2014).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Yang, Y.-T., Callegari, C., Feng, X. L., Ekinci, K. L. & Roukes, M. L. Zeptogram-scale nanomechanical mass sensing. Nano Lett. 6<\/b>, 583\u2013586 (2006).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Sage, E. et al. Neutral particle mass spectrometry with nanomechanical systems. Nat. Commun. 6<\/b>, 6482 (2015).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Schimmele, L., Napi\u00f3rkowski, M. & Dietrich, S. Conceptual aspects of line tensions. J. Chem. Phys. 127<\/b>, 164715 (2007).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Jasper, W. J. & Anand, N. A generalized variational approach for predicting contact angles of sessile nano-droplets on both flat and curved surfaces. J. Mol. Liq. 281<\/b>, 196\u2013203 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Getta, T. & Dietrich, S. Line tension between fluid phases and a substrate. Phys. Rev. E 57<\/b>, 655 (1998).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Chou, T. Geometry-dependent electrostatics near contact lines. Phys. Rev. Lett. 87<\/b>, 106101 (2001).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Jakubczyk, P. & Napi\u00f3rkowski, M. The influence of droplet size on line tension. J. Phys. Condens. Matter 16<\/b>, 6917 (2004).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Werder, T., Walther, J. H., Jaffe, R. L., Halicioglu, T. & Koumoutsakos, P. On the water\u2013carbon interaction for use in molecular dynamics simulations of graphite and carbon nanotubes. J. Phys. Chem. B 107<\/b>, 1345\u20131352 (2003).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Gaydos, J. & Neumann, A. W. The dependence of contact angles on drop size and line tension. J. Colloid Interface Sci. 120<\/b>, 76\u201386 (1987).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Wang, J. Y., Betelu, S. & Law, B. M. Line tension effects near first-order wetting transitions. Phys. Rev. Lett. 83<\/b>, 3677 (1999).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Pompe, T. & Herminghaus, S. Three-phase contact line energetics from nanoscale liquid surface topographies. Phys. Rev. Lett. 85<\/b>, 1930 (2000).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Pompe, T. Line tension behavior of a first-order wetting system. Phys. Rev. Lett. 89<\/b>, 076102 (2002).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Amirfazli, A., Keshavarz, A., Zhang, L. & Neumann, A. W. Determination of line tension for systems near wetting. J. Colloid Interface Sci. 265<\/b>, 152\u2013160 (2003).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Checco, A., Guenoun, P. & Daillant, J. Nonlinear dependence of the contact angle of nanodroplets on contact line curvature. Phys. Rev. Lett. 91<\/b>, 186101 (2003).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Dutta, R. C., Khan, S. & Singh, J. K. Wetting transition of water on graphite and boron-nitride surfaces: A molecular dynamics study. Fluid Phase Equilib. 302<\/b>, 310\u2013315 (2011).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhang, J., Wang, P., Borg, M. K., Reese, J. M. & Wen, D. A critical assessment of the line tension determined by the modified Young\u2019s equation. Phys. Fluids 30<\/b>, 082003 (2018).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Tolman, R. C. The effect of droplet size on surface tension. J. Chem. Phys. 17<\/b>, 333\u2013337 (1949).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Vargaftik, N., Volkov, B. N. & Voljak, L. International tables of the surface tension of water. J. Phys. Chem. Ref. Data 12<\/b>, 817\u2013820 (1983).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Amirfazli, A. & Neumann, A. Status of the three-phase line tension: a review. Adv. Colloid Interface Sci. 110<\/b>, 121\u2013141 (2004).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Kandu\u010d, M. & Netz, R. R. Atomistic simulations of wetting properties and water films on hydrophilic surfaces. J. Chem. Phys. 146<\/b>, 164705 (2017).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Ma, R. et al. Atomic imaging of the edge structure and growth of a two-dimensional hexagonal ice. Nature 577<\/b>, 60\u201363 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Chen, J. et al. An unconventional bilayer ice structure on a NaCl (001) film. Nat. Commun. 5<\/b>, 4056 (2014).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Demmenie, M. et al. Partial wetting of water on ice. Phys. Rev. Fluids 10<\/b>, 054002 (2025).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Gonella, G. et al. Water at charged interfaces. Nat. Rev. Chem. 5<\/b>, 466\u2013485 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Vega, C. & de Miguel, E. Surface tension of the most popular models of water by using the test-area simulation method. J. Chem. Phys. 126<\/b>, 154707 (2007).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Joswiak, M. N., Do, R., Doherty, M. F. & Peters, B. Energetic and entropic components of the Tolman length for mW and TIP4P\/2005 water nanodroplets. J. Chem. Phys. 145<\/b>, 204703 (2016).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Olofsson, G. & Hepler, L. G. Thermodynamics of ionization of water over wide ranges of temperature and pressure. J. Solut. Chem. 4<\/b>, 127\u2013143 (1975).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Bandura, A. V. & Lvov, S. N. The ionization constant of water over wide ranges of temperature and density. J. Phys. Chem. Ref. Data 35<\/b>, 15\u201330 (2006).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Calegari Andrade, M., Car, R. & Selloni, A. Probing the self-ionization of liquid water with ab initio deep potential molecular dynamics. Proc. Natl Acad. Sci. USA 120<\/b>, e2302468120 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Di Pino, S. et al. Water self-dissociation is insensitive to nanoscale environments. Angew. Chem. Int. Ed. 62<\/b>, e202306526 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Dasgupta, S., Cassone, G. & Paesani, F. Nuclear quantum effects and the Grotthuss mechanism dictate the ph of liquid water. J. Phys. Chem. Lett. 16<\/b>, 2996\u20133003 (2025).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Munoz-Santiburcio, D. & Marx, D. Nanoconfinement in slit pores enhances water self-dissociation. Phys. Rev. Lett. 119<\/b>, 056002 (2017).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Advincula, X. R. et al. How reactive is water at the nanoscale and how to control it?. Preprint at https:\/\/arxiv.org\/abs\/2508.13034<\/a> (2025).<\/p>\n<\/li>\n

  • \n

    Naikade, M. et al. Studying the wettability of Si and eutectic Si\u2013Zr alloy on carbon and silicon carbide by sessile drop experiments. J. Eur. Ceram. Soc. 39<\/b>, 735\u2013742 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Factorovich, M. H., Molinero, V. & Scherlis, D. A. A simple grand canonical approach to compute the vapor pressure of bulk and finite size systems. J. Chem. Phys. 140<\/b>, 064111 (2014).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Plimpton, S. Fast parallel algorithms for short-range molecular dynamics. J. Comput. Phys. 117<\/b>, 1\u201319 (1995).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Coe, M. K., Evans, R. & Wilding, N. B. The coexistence curve and surface tension of a monatomic water model. J. Chem. Phys. 156<\/b>, 154505 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Russo, J., Romano, F. & Tanaka, H. New metastable form of ice and its role in the homogeneous crystallization of water. Nat. Mater. 13<\/b>, 733\u2013739 (2014).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Sun, G. & Tanaka, H. Surface-induced water crystallisation driven by precursors formed in negative pressure regions. Nat. Commun. 15<\/b>, 6083 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Lin, S.-T., Blanco, M. & Goddard, W. A. III The two-phase model for calculating thermodynamic properties of liquids from molecular dynamics: validation for the phase diagram of lennard-jones fluids. J. Chem. Phys. 119<\/b>, 11792\u201311805 (2003).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Lin, S.-T., Maiti, P. K. & Goddard, W. A. III Two-phase thermodynamic model for efficient and accurate absolute entropy of water from molecular dynamics simulations. J. Phys. Chem. B 114<\/b>, 8191\u20138198 (2010).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    McQuarrie, D. A. Statistical Mechanics (Harper & Row, 1976).<\/p>\n<\/li>\n

  • \n

    Lechner, W. & Dellago, C. Accurate determination of crystal structures based on averaged local bond order parameters. J. Chem. Phys. 129<\/b>, 114707 (2008).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n","protected":false},"excerpt":{"rendered":"Bonn, D., Eggers, J., Indekeu, J., Meunier, J. & Rolley, E. Wetting and spreading. Rev. Mod. Phys. 81,…\n","protected":false},"author":2,"featured_media":545281,"comment_status":"","ping_status":"","sticky":false,"template":"","format":"standard","meta":{"footnotes":"","_share_on_mastodon":"0"},"categories":[271],"tags":[3554,22299,3553,3557,914,18,20438,910,19,22795,17,3552,3555,3556,452,133,57071,22794,3551],"class_list":["post-545280","post","type-post","status-publish","format-standard","has-post-thumbnail","category-physics","tag-atomic","tag-chemical-physics","tag-classical-and-continuum-physics","tag-complex-systems","tag-condensed-matter-physics","tag-eire","tag-fluids","tag-general","tag-ie","tag-interfaces-and-thin-films","tag-ireland","tag-mathematical-and-computational-physics","tag-molecular","tag-optical-and-plasma-physics","tag-physics","tag-science","tag-structural-properties","tag-surfaces","tag-theoretical"],"share_on_mastodon":{"url":"https:\/\/pubeurope.com\/@ie\/116782808675841676","error":""},"_links":{"self":[{"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/posts\/545280","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/comments?post=545280"}],"version-history":[{"count":0,"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/posts\/545280\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/media\/545281"}],"wp:attachment":[{"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/media?parent=545280"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/categories?post=545280"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.europesays.com\/ie\/wp-json\/wp\/v2\/tags?post=545280"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}