The donation also includes personal protective gear, water rescue tools, and road traffic collision equipment.
The donation will have no impact on frontline services or existing commitments, Avon Fire and Rescue Service said.
Mr Goggin went on to explain how the donation was a “powerful example” of how UK fire services could help those “facing unimaginable hardship”.
“Travelling with our crews to deliver this equipment is a privilege,” he said.
“This isn’t just about vehicles – it’s about people.
“We want the people of Ukraine to know they’re not alone.”
Mr Goggin is set to join the firefighters on their journey to Ukraine later this year.