{"id":118087,"date":"2025-05-20T21:34:15","date_gmt":"2025-05-20T21:34:15","guid":{"rendered":"https:\/\/www.europesays.com\/uk\/118087\/"},"modified":"2025-05-20T21:34:15","modified_gmt":"2025-05-20T21:34:15","slug":"vortices-and-antivortices-in-antiferroelectric-pbzro3","status":"publish","type":"post","link":"https:\/\/www.europesays.com\/uk\/118087\/","title":{"rendered":"Vortices and antivortices in antiferroelectric PbZrO3"},"content":{"rendered":"
  • \n

    Rodriguez, B. J. et al. Vortex polarization states in nanoscale ferroelectric arrays. Nano Lett. 9<\/b>, 1127\u20131131 (2009).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Jia, C. L., Urban, K. W., Alexe, M., Hesse, D. & Vrejoiu, I. Direct observation of continuous electric dipole rotation in flux-closure domains in ferroelectric Pb(Zr,Ti)O3. Science 331<\/b>, 1420\u20131423 (2011).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Nelson, C. T. et al. Spontaneous vortex nanodomain arrays at ferroelectric heterointerfaces. Nano Lett. 11<\/b>, 828\u2013834 (2011).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Tang, Y. L. et al. Observation of a periodic array of flux-closure quadrants in strained ferroelectric PbTiO3 films. Science 348<\/b>, 547\u2013551 (2015).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Yadav, A. K. et al. Observation of polar vortices in oxide superlattices. Nature 530<\/b>, 198\u2013201 (2016).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Liu, Y. et al. Large scale two-dimensional flux-closure domain arrays in oxide multilayers and their controlled growth. Nano Lett. 17<\/b>, 7258\u20137266 (2017).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Das, S. et al. Observation of room-temperature polar skyrmions. Nature 568<\/b>, 368\u2013372 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Luk\u2019yanchuk, I., Tikhonov, Y., Razumnaya, A. & Vinokur, V. M. Hopfions emerge in ferroelectrics. Nat. Commun. 11<\/b>, 2423 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Luk\u2019yanchuk I., Razumnaya A., Kondovych S., Tikhonov Y. & Vinokur V. M. Topological ferroelectric chirality. Preprint at https:\/\/arxiv.org\/abs\/2406.19728<\/a> (2024).<\/p>\n<\/li>\n

  • \n

    Naumov, I. I., Bellaiche, L. & Fu, H. X. Unusual phase transitions in ferroelectric nanodisks and nanorods. Nature 432<\/b>, 737\u2013740 (2004).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Jung, H. et al. Logic operations based on magnetic-vortex-state networks. ACS Nano 6<\/b>, 3712\u20133717 (2012).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Yadav, A. K. et al. Spatially resolved steady-state negative capacitance. Nature 565<\/b>, 468\u2013471 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Balke, N. et al. Enhanced electric conductivity at ferroelectric vortex cores in BiFeO3. Nat. Phys. 8<\/b>, 81\u201388 (2012).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Aguado-Puente, P. & Junquera, J. Ferromagneticlike closure domains in ferroelectric ultrathin films: first-principles simulations. Phys. Rev. Lett. 100<\/b>, 177601 (2008).<\/p>\n

    Article<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Kittel, C. Theory of antiferroelectric crystals. Phys. Rev. 82<\/b>, 729\u2013732 (1951).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Shirane, G., Sawaguchi, E. & Takagi, Y. Dielectric properties of lead zirconate. Phys. Rev. 84<\/b>, 476\u2013481 (1951).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Sawaguchi, E., Maniwa, H. & Hoshino, S. Antiferroelectric structure of lead zirconate. Phys. Rev. 83<\/b>, 1078\u20131078 (1951).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Corker, D. L., Glazer, A. M., Dec, J., Roleder, K. & Whatmore, R. W. A re-investigation of the crystal structure of the perovskite PbZrO3 by X-ray and neutron diffraction. Acta Cryst. B 53<\/b>, 135\u2013142 (1997).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Sapriel, J. Domain-wall orientations in ferroelastics. Phys. Rev. B 12<\/b>, 5128\u20135140 (1975).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Liu, Y. et al. Controlled growth and atomic-scale mapping of charged heterointerfaces in PbTiO3\/BiFeO3 bilayers. ACS Appl. Mater. Interfaces 9<\/b>, 25578\u201325586 (2017).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Wang, W. Y. et al. Atomic level 1D structural modulations at the negatively charged domain walls in BiFeO3 films. Adv. Mater. Interfaces 2<\/b>, 1500024 (2015).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Tang, Y. L. et al. Atomic-scale mapping of dipole frustration at 90\u00b0 charged domain walls in ferroelectric PbTiO3 films. Sci. Rep. 4<\/b>, 4115 (2014).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     PubMed Central<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Ma, T., Fan, Z., Tan, X. & Zhou, L. Atomically resolved domain boundary structure in lead zirconate-based antiferroelectrics. Appl. Phys. Lett. 115<\/b>, 122902 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Nord, M., Vullum, P. E., MacLaren, I., Tybell, T. & Holmestad, R. Atomap: a new software tool for the automated analysis of atomic resolution images using two-dimensional Gaussian fitting. Adv. Struct. Chem. Imaging 3<\/b>, 9 (2017).<\/p>\n

    Article<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     PubMed Central<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Liu, Y. et al. Translational boundaries as incipient ferrielectric domains in antiferroelectric PbZrO3. Phys. Rev. Lett. 130<\/b>, 216801 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Liu, Y. et al. Atomic coordinates and polarization map around a pair of 1\/2 a[01\\(\\bar{1}\\)] dislocation cores produced by plastic deformation in relaxor ferroelectric PIN-PMN-PT. J. Appl. Phys. 129<\/b>, 234101 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Cabral, M. J., Chen, Z. & Liao, X. Scanning transmission electron microscopy for advanced characterization of ferroic materials. Microstructures 3<\/b>, 2023040 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Moore, K. et al. Charged domain wall and polar vortex topologies in a room-temperature magnetoelectric multiferroic thin film. ACS Appl. Mater. Interfaces 14<\/b>, 5525\u20135536 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     PubMed Central<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Hong, Z. et al. Vortex domain walls in ferroelectrics. Nano Lett. 21<\/b>, 3533\u20133539 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Li, F., Nattermann, T. & Pokrovsky, V. L. Vortex domain walls in helical magnets. Phys. Rev. Lett. 108<\/b>, 107203 (2012).<\/p>\n

    Article<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Mermin, N. D. The topological theory of defects in ordered media. Rev. Mod. Phys. 51<\/b>, 591\u2013648 (1979).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhang, H. et al. Finite-temperature properties of the antiferroelectric perovskite PbZrO3 from a deep-learning interatomic potential. Phys. Rev. B 110<\/b>, 054109 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Shapovalov, K. & Stengel, M. Tilt-driven antiferroelectricity in PbZrO3. Phys. Rev. Mater. 7<\/b>, L071401 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Abid, A. Y. et al. Creating polar antivortex in PbTiO3\/SrTiO3 superlattice. Nat. Commun. 12<\/b>, 2054 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     PubMed Central<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Hu, T. et al. Hierarchical domain structures in (Pb,La)(Zr, Sn, Ti)O3 antiferroelectric ceramics. Ceram. Int. 46<\/b>, 22575 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    S\u00e1nchez-Santolino, G. et al. A 2D ferroelectric vortex pattern in twisted BaTiO3 freestanding layers. Nature 626<\/b>, 529\u2013534 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     PubMed Central<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    MacLaren, I., Villaurrutia, R., Schaffer, B., Houben, L., & Pel\u00e1iz-Barranco, A. Atomic-scale imaging and quantification of electrical polarisation in incommensurate antiferroelectric lanthanum-doped lead zirconate titanate. Adv. Funct. Mater. 22<\/b>, 261\u2013266 (2012).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Fu, Z. et al. Unveiling the ferrielectric nature of PbZrO3-based antiferroelectric materials. Nat. Commun. 11<\/b>, 3809 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     PubMed Central<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Ma, T. et al. Uncompensated polarization in incommensurate modulations of perovskite antiferroelectrics. Phys. Rev. Lett. 123<\/b>, 217602 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Wei, X.-K., Jia, C.-L., Roleder, K., Dunin-Borkowski, R. E. & Mayer, J. In situ observation of point-defect-induced unit-cell-wise energy storage pathway in antiferroelectric PbZrO3. Adv. Funct. Mater. 31<\/b>, 2008609 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Thompson, A. P., Aktulga, H. M. & Berger, R. LAMMPS\u2014a flexible simulation tool for particle-based materials modeling at the atomic, meso, and continuum scales. Comput. Phys. Commun. 271<\/b>, 108171 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n","protected":false},"excerpt":{"rendered":"Rodriguez, B. J. et al. Vortex polarization states in nanoscale ferroelectric arrays. Nano Lett. 9, 1127\u20131131 (2009). Article\u00a0…\n","protected":false},"author":2,"featured_media":118088,"comment_status":"","ping_status":"","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[3845],"tags":[31328,11704,12373,3968,22098,31329,12795,74,70,52851,16,15],"class_list":{"0":"post-118087","1":"post","2":"type-post","3":"status-publish","4":"format-standard","5":"has-post-thumbnail","7":"category-physics","8":"tag-biomaterials","9":"tag-condensed-matter-physics","10":"tag-ferroelectrics-and-multiferroics","11":"tag-general","12":"tag-materials-science","13":"tag-nanotechnology","14":"tag-optical-and-electronic-materials","15":"tag-physics","16":"tag-science","17":"tag-topological-defects","18":"tag-uk","19":"tag-united-kingdom"},"share_on_mastodon":{"url":"https:\/\/pubeurope.com\/@uk\/114542311125916790","error":""},"_links":{"self":[{"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/posts\/118087","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/comments?post=118087"}],"version-history":[{"count":0,"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/posts\/118087\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/media\/118088"}],"wp:attachment":[{"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/media?parent=118087"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/categories?post=118087"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/tags?post=118087"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}