{"id":592448,"date":"2025-11-25T08:26:20","date_gmt":"2025-11-25T08:26:20","guid":{"rendered":"https:\/\/www.europesays.com\/uk\/592448\/"},"modified":"2025-11-25T08:26:20","modified_gmt":"2025-11-25T08:26:20","slug":"spontaneous-2d-perovskite-formation-at-the-buried-interface-of-perovskite-solar-cells-enhances-crystallization-uniformity-and-defect-passivation","status":"publish","type":"post","link":"https:\/\/www.europesays.com\/uk\/592448\/","title":{"rendered":"Spontaneous 2D perovskite formation at the buried interface of perovskite solar cells enhances crystallization uniformity and defect passivation"},"content":{"rendered":"
  • \n

    Min, H. et al. Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes. Nature 598<\/b>, 444\u2013450 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Luo, C. et al. Engineering the buried interface in perovskite solar cells via lattice-matched electron transport layer. Nat. Photon. 35<\/b>, 2303139 (2023).<\/p>\n


    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Wang, F. et al. Two-step perovskite solar cells with >25% efficiency: unveiling the hidden bottom surface of perovskite layer. Adv. Mater. 36<\/b>, 2401476 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Chen, S. et al. Stabilizing perovskite-substrate interfaces for high-performance perovskite modules. Science 373<\/b>, 902\u2013907 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Chen, S. et al. Crystallization in one-step solution deposition of perovskite films: upward or downward? Sci. Adv. 7<\/b>, eabb2412 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Liu, S. et al. Buried interface molecular hybrid for inverted perovskite solar cells. Nature 632<\/b>, 536\u2013542 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Xiao, Y., Yang, X., Zhu, R. & Snaith, H. J. Unlocking interfaces in photovoltaics. Science 384<\/b>, 846\u2013848 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Shi, P. J. et al. Oriented nucleation in formamidinium perovskite for photovoltaics. Nature 620<\/b>, 323\u2013327 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Park, J. et al. Controlled growth of perovskite layers with volatile alkylammonium chlorides. Nature 616<\/b>, 724\u2013730 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Huang, Z. et al. Anion-\u03c0 interactions suppress phase impurities in FAPbI3 solar cells. Nature 623<\/b>, 531\u2013537 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Gao, Y. et al. Controlled nucleation and oriented crystallization of methylammonium-free perovskites via in situ generated 2D perovskite phases. Adv. Mater. 36<\/b>, 2405921 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Azmi, R. et al. Double-side 2-dimensional\/3-dimensional heterojunctions for inverted perovskite solar cells. Nature 628<\/b>, 93\u201398 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Li, H. Y. et al. 2D\/3D heterojunction engineering at the buried interface towards high-performance inverted methylammonium-free perovskite solar cells. Nat. Energy 8<\/b>, 946\u2013955 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Wang, Y. et al. Highly oriented FAPbI3 via 2D Ruddlesden Popper perovskite template growth. Adv. Energy Mater. 14<\/b>, 2401721 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Li, Q. et al. Harmonizing the bilateral bond strength of the interfacial molecule in perovskite solar cells. Nat. Energy 9<\/b>, 1506\u20131516 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Song, S. et al. Molecular engineering of organic spacer cations for efficient and stable formamidinium perovskite solar cell. Adv. Energy Mater. 10<\/b>, 2001759 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Park, S. M. et al. Engineering ligand reactivity enables high-temperature operation of stable perovskite solar cells. Science 381<\/b>, 209\u2013215 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Azmi, R. et al. Damp heat-stable perovskite solar cells with tailored-dimensionality 2D\/3D heterojunctions. Science 376<\/b>, 73\u201377 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Sidhik, S. et al. Deterministic fabrication of 3D\/2D perovskite bilayer stacks for durable and efficient solar cells. Science 377<\/b>, 1425\u20131430 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Wang, J. et al. Bilayer interface engineering through 2D\/3D perovskite and surface dipole for inverted perovskite solar modules. eScience 4<\/b>, 100308 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhou, T. et al. Crystal growth regulation of 2D\/3D perovskite films for solar cells with both high efficiency and stability. Adv. Mater. 34<\/b>, 2200705 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhang, C. et al. Work function tuning of a weak adhesion homojunction for stable perovskite solar cells. Joule 8<\/b>, 1394\u20131411 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Cho, H. et al. Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes. Science 350<\/b>, 1222\u20131225 (2015).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhao, Y. et al. Inactive (PbI2)2RbCl stabilizes perovskite films for efficient solar cells. Science 377<\/b>, 531\u2013534 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Gao, H. et al. Homogeneous crystallization and buried interface passivation for perovskite tandem solar modules. Science 383<\/b>, 855\u2013859 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Meng, R. et al. Solvent bath annealing-induced liquid phase Ostwald ripening enabling efficient and stable perovskite solar cells. J. Mater. Chem. A 11<\/b>, 4780\u20134788 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Li, N. et al. Liquid medium annealing for fabricating durable perovskite solar cells with improved reproducibility. Science 373<\/b>, 561\u2013567 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Liu, C. et al. Two-dimensional perovskitoids enhance stability in perovskite solar cells. Nature 633<\/b>, 359\u2013364 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhang, K. et al. Highly efficient and stable FAPbI3 perovskite solar cells and modules based on exposure of the (011) facet. Nano-Micro Lett. 15<\/b>, 138 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Krogmeier, B., Staub, F., Grabowski, D., Rau, U. & Kirchartz, T. Quantitative analysis of the transient photoluminescence of CH3NH3PbI3\/PC61BM heterojunctions by numerical simulations. Sustain. Energy Fuels 2<\/b>, 1027\u20131034 (2018).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Jennings, W. B., Farrell, B. M. & Malone, J. F. Attractive intramolecular edge-to-face aromatic interactions in flexible organic molecules. Acc. Chem. Res. 34<\/b>, 885\u2013894 (2001).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Bai, M. et al. A donor-acceptor-donor structured organic conductor with S\u00b7\u00b7\u00b7S chalcogen bonding. Cryst. Growth Des. 14<\/b>, 459\u2013466 (2014).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Tan, Q. et al. Inverted perovskite solar cells using dimethylacridine-based dopants. Nature 620<\/b>, 545\u2013551 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Shao, J.-Y. et al. Recent progress in perovskite solar cells: material science. Sci. China Chem. 66<\/b>, 10\u201364 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Liu, Y., Guo, J., Zhou, H., Li, C. & Guo, X. Correlating \u03c0-\u03c0 stacking of aromatic diammoniums with stability and dimensional reduction of Dion-Jacobson 2D perovskites. J. Am. Chem. Soc. 146<\/b>, 8198\u20138205 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Lee, J. W. et al. 2D perovskite stabilized phase-pure formamidinium perovskite solar cells. Nat. Commun. 9<\/b>, 3021 (2018).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhou, T. et al. Highly efficient and stable solar cells based on crystalline oriented 2D\/3D hybrid perovskite. Adv. Mater. 31<\/b>, 1901242 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Lin, Y. et al. Unveiling the operation mechanism of layered perovskite solar cells. Nat. Commun. 10<\/b>, 1008 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Hoffman, J. M. et al. Film formation mechanisms in mixed-dimensional 2D\/3D halide perovskite films revealed by in situ grazing-incidence wide-angle X-ray scattering. Chem 8<\/b>, 1067\u20131082 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Quintero-Bermudez, R. et al. Ligand-induced surface charge density modulation generates local type-II band alignment in reduced-dimensional perovskites. J. Am. Chem. Soc. 141<\/b>, 13459\u201313467 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Yu, D. et al. Direct observation of photoinduced carrier blocking in mixed-dimensional 2D\/3D perovskites and the origin. Nat. Commun. 13<\/b>, 6229 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Jang, Y.-W. et al. Intact 2D\/3D halide junction perovskite solar cells via solid-phase in-plane growth. Nat. Energy 6<\/b>, 63\u201371 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Julien, A., Puel, J.-B. & Guillemoles, J.-F. Distinction of mechanisms causing experimental degradation of perovskite solar cells by simulating associated pathways. Energy Environ. Sci. 16<\/b>, 190\u2013200 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhao, B. X. et al. A hole-transport material that also passivates perovskite surface defects for solar cells with improved efficiency and stability. Energy Environ. Sci. 13<\/b>, 4334\u20134343 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Lai, H. et al. Two-dimensional Ruddlesden-Popper perovskite with nanorod-like morphology for solar cells with efficiency exceeding 15. J. Am. Chem. Soc. 140<\/b>, 11639\u201311646 (2018).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n","protected":false},"excerpt":{"rendered":"Min, H. et al. Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes. Nature 598, 444\u2013450 (2021).…\n","protected":false},"author":2,"featured_media":592449,"comment_status":"","ping_status":"","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[3845],"tags":[14906,3968,74,11112,70,39881,16,15],"class_list":{"0":"post-592448","1":"post","2":"type-post","3":"status-publish","4":"format-standard","5":"has-post-thumbnail","7":"category-physics","8":"tag-applied-and-technical-physics","9":"tag-general","10":"tag-physics","11":"tag-quantum-physics","12":"tag-science","13":"tag-solar-cells","14":"tag-uk","15":"tag-united-kingdom"},"share_on_mastodon":{"url":"https:\/\/pubeurope.com\/@uk\/115609389385280820","error":""},"_links":{"self":[{"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/posts\/592448","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/comments?post=592448"}],"version-history":[{"count":0,"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/posts\/592448\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/media\/592449"}],"wp:attachment":[{"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/media?parent=592448"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/categories?post=592448"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.europesays.com\/uk\/wp-json\/wp\/v2\/tags?post=592448"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}