{"id":841058,"date":"2026-06-03T08:19:33","date_gmt":"2026-06-03T08:19:33","guid":{"rendered":"https:\/\/www.europesays.com\/us\/841058\/"},"modified":"2026-06-03T08:19:33","modified_gmt":"2026-06-03T08:19:33","slug":"uv-and-thermally-stable-hole-selective-contacts-with-enhanced-assembly-density-for-inverted-perovskite-solar-cells","status":"publish","type":"post","link":"https:\/\/www.europesays.com\/us\/841058\/","title":{"rendered":"UV and thermally stable hole-selective contacts with enhanced assembly density for inverted perovskite solar cells"},"content":{"rendered":"
  • \n

    Snaith, H. J. Present status and future prospects of perovskite photovoltaics. Nat. Mater. 17<\/b>, 372\u2013376 (2018).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Park, S. M. et al. Low-loss contacts on textured substrates for inverted perovskite solar cells. Nature 624<\/b>, 289\u2013294 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Lin, R. et al. All-perovskite tandem solar cells with improved grain surface passivation. Nature 603<\/b>, 73\u201378 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Azmi, R. et al. Double-side 2D\/3D heterojunctions for inverted perovskite solar cells. Nature 628<\/b>, 93\u201398 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Shen, Z. et al. Precise synthesis of advanced polyarylamines for efficient perovskite solar cells. Nat. Mater. 24<\/b>, 1450\u20131456 (2025).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Wang, Y. et al. Teaching an old anchoring group new tricks: enabling low-cost, eco-friendly hole-transporting materials for efficient and stable perovskite solar cells. J. Am. Chem. Soc. 142<\/b>, 16632\u201316643 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    He, R. et al. Improving interface quality for 1-cm2 all-perovskite tandem solar cells. Nature 618<\/b>, 80\u201386 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhao, K. et al. Peri-fused polyaromatic molecular contacts for perovskite solar cells. Nature 632<\/b>, 301\u2013306 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Al-Ashouri, A. et al. Conformal monolayer contacts with lossless interfaces for perovskite single junction and monolithic tandem solar cells. Energy Environ. Sci. 12<\/b>, 3356\u20133369 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Li, Z. et al. Stabilized hole-selective layer for high-performance inverted p\u2013i\u2013n perovskite solar cells. Science 382<\/b>, 284\u2013289 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Qu, G. et al. Conjugated linker-boosted self-assembled monolayer molecule for inverted perovskite solar cells. Joule 8<\/b>, 2123\u20132134 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Magomedov, A. et al. Self-assembled hole transporting monolayer for highly efficient perovskite solar cells. Adv. Energy Mater. 8<\/b>, 1801892 (2018).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Jiang, W. et al. \u03c0-Expanded carbazoles as hole-selective self-assembled monolayers for high-performance perovskite solar cells. Angew. Chem. Int. Ed. 134<\/b>, e202213560 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Paniagua, S. A. et al. Phosphonic acids for interfacial engineering of transparent conductive oxides. Chem. Rev. 116<\/b>, 7117\u20137158 (2016).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Li, M., Liu, M., Qi, F., Lin, F. R. & Jen, A. K.-Y. Self-assembled monolayers for interfacial engineering in solution-processed thin-film electronic devices: design, fabrication, and applications. Chem. Rev. 124<\/b>, 2138\u20132204 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Luo, C. et al. Engineering bonding sites enables uniform and robust self-assembled monolayer for stable perovskite solar cells. Nat. Mater. 24<\/b>, 1265\u20131272 (2025).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Ji, X. et al. Efficient wide-bandgap perovskite solar cells with open-circuit voltage deficit below 0.4 V via hole-selective interface engineering. Sci. China Chem. 67<\/b>, 2102\u20132110 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhan, L., Zhang, L., Li, Y., Cai, H. & Wu, Y. Performance and stability enhancement of hole-transporting materials in inverted perovskite solar cells. ACS Appl. Energy Mater. 8<\/b>, 3985\u20133996 (2025).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhou, J. et al. Molecular contacts with an orthogonal \u03c0-skeleton induce amorphization to enhance perovskite solar cell performance. Nat. Chem. 17<\/b>, 564\u2013570 (2025).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhang, S. et al. Self-assembled \u03c0-conjugated hole-selective molecules for UV-resistant high-efficiency perovskite solar cells. Angew. Chem. Int. Ed. 64<\/b>, e202508782 (2025).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Li, C. et al. Fully aromatic self-assembled hole-selective layer toward efficient inverted wide-bandgap perovskite solar cells with ultraviolet resistance. Angew. Chem. Int. Ed. 63<\/b>, e202315281 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Wan, X. et al. Thermal stability of phosphonic acid self-assembled monolayers on alumina substrates. J. Phys. Chem. C 124<\/b>, 2531\u20132542 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Atanasov, V. et al. Synergistically integrated phosphonated poly(pentafluorostyrene) for fuel cells. Nat. Mater. 20<\/b>, 370\u2013377 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Fei, C. et al. Strong-bonding hole-transport layers reduce ultraviolet degradation of perovskite solar cells. Science 384<\/b>, 1126\u20131134 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Luo, C. et al. Engineering the buried interface in perovskite solar cells via lattice-matched electron transport layer. Nat. Photon. 17<\/b>, 856\u2013864 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhan, L. et al. Reinforced perovskite-substrate interfaces via multi-sited and dual-sided anchoring. Adv. Mater. 37<\/b>, 2506048 (2025).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Chen, X. et al. Studies on the effect of solvents on self-assembled monolayers formed from organophosphonic acids on indium tin oxide. Langmuir 28<\/b>, 9487\u20139495 (2012).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhang, S. et al. Minimizing buried interfacial defects for efficient inverted perovskite solar cells. Science 380<\/b>, 404\u2013409 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Tang, H. et al. Reinforcing self-assembly of hole transport molecules for stable inverted perovskite solar cells. Science 383<\/b>, 1236\u20131240 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Isikgor, F. H. et al. Molecular engineering of contact interfaces for high-performance perovskite solar cells. Nat. Rev. Mater. 8<\/b>, 89\u2013108 (2022).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Jiang, W. et al. Toughened self-assembled monolayers for durable perovskite solar cells. Nature 646<\/b>, 95\u2013101 (2025).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Anderson, K. L. & Edwards, M. A. A tutorial for scanning electrochemical cell microscopy (SECCM) measurements: step-by-step instructions, visual resources, and guidance for first experiments. ACS Meas. Sci. Au 5<\/b>, 160\u2013177 (2025).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     PubMed Central<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Wu, W. et al. Stable and uniform self-assembled organic diradical molecules for perovskite photovoltaics. Science 389<\/b>, 195\u2013199 (2025).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Ulman, A. Formation and structure of self-assembled monolayers. Chem. Rev. 96<\/b>, 1533\u20131554 (1996).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Zhang, S., Baker, J. & Pulay, P. A reliable and efficient first principles-based method for predicting pKa values. 1. Methodology. J. Phys. Chem. A 114<\/b>, 425\u2013431 (2010).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Liptak, M. D. & Shields, G. C. Accurate p Ka calculations for carboxylic acids using complete basis set and gaussian-n models combined with CPCM continuum solvation methods. J. Am. Chem. Soc. 123<\/b>, 7314\u20137319 (2001).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Frisch, M. J., Head-Gordon, M. & Pople, J. A. A direct MP2 gradient method. Chem. Phys. Lett. 166<\/b>, 275\u2013280 (1990).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Kresse, G. & Furthm\u00fcller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 54<\/b>, 11169\u201311186 (1996).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Bl\u00f6chl, P. E. Projector augmented-wave method. Phys. Rev. B 50<\/b>, 17953\u201317979 (1994).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Goedecker, S., Teter, M. & Hutter, J. Separable dual-space Gaussian pseudopotentials. Phys. Rev. B 54<\/b>, 1703\u20131710 (1996).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Lee, K., Murray, \u00c9D., Kong, L., Lundqvist, B. I. & Langreth, D. C. Higher-accuracy van der Waals density functional. Phys. Rev. B 82<\/b>, 081101 (2010).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n","protected":false},"excerpt":{"rendered":"Snaith, H. J. Present status and future prospects of perovskite photovoltaics. Nat. Mater. 17, 372\u2013376 (2018). Article\u00a0 CAS\u00a0…\n","protected":false},"author":3,"featured_media":841059,"comment_status":"","ping_status":"","sticky":false,"template":"","format":"standard","meta":{"footnotes":"","_share_on_mastodon":"0"},"categories":[25],"tags":[26985,2270,344428,834,19533,26986,26984,492,159,190964,67,132,68],"class_list":["post-841058","post","type-post","status-publish","format-standard","has-post-thumbnail","category-physics","tag-biomaterials","tag-condensed-matter-physics","tag-electronic-materials","tag-general","tag-materials-science","tag-nanotechnology","tag-optical-and-electronic-materials","tag-physics","tag-science","tag-solar-cells","tag-united-states","tag-unitedstates","tag-us"],"share_on_mastodon":{"url":"https:\/\/pubeurope.com\/@us\/116685200920567421","error":""},"_links":{"self":[{"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/posts\/841058","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/comments?post=841058"}],"version-history":[{"count":0,"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/posts\/841058\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/media\/841059"}],"wp:attachment":[{"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/media?parent=841058"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/categories?post=841058"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/tags?post=841058"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}