{"id":843120,"date":"2026-06-04T05:36:15","date_gmt":"2026-06-04T05:36:15","guid":{"rendered":"https:\/\/www.europesays.com\/us\/843120\/"},"modified":"2026-06-04T05:36:15","modified_gmt":"2026-06-04T05:36:15","slug":"mechanophore-cross-linking-enhances-ballistic-energy-dissipation-of-polymers","status":"publish","type":"post","link":"https:\/\/www.europesays.com\/us\/843120\/","title":{"rendered":"Mechanophore cross-linking enhances ballistic energy dissipation of polymers"},"content":{"rendered":"
  • \n

    Siviour, C. R. & Jordan, J. L. High strain rate mechanics of polymers: a review. J. Dyn. Behav. Mater. 2<\/b>, 15\u201332 (2016).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Giuntoli, A. & Keten, S. Tuning star architecture to control mechanical properties and impact resistance of polymer thin films. Cell Rep. Phys. Sci. 2<\/b>, 100596 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Levita, G., De Petris, S., Marchetti, A. & Lazzeri, A. Crosslink density and fracture toughness of epoxy resins. J. Mater. Sci. 26<\/b>, 2348\u20132352 (1991).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Caruso, M. M. et al. Mechanically-induced chemical changes in polymeric materials. Chem. Rev. 109<\/b>, 5755\u20135798 (2009).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Li, J., Nagamani, C. & Moore, J. S. Polymer mechanochemistry: from destructive to productive. Acc. Chem. Res. 48<\/b>, 2181\u20132190 (2015).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Chen, Y., Mellot, G., van Luijk, D., Creton, C. & Sijbesma, R. P. Mechanochemical tools for polymer materials. Chem. Soc. Rev. 50<\/b>, 4100\u20134140 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Brown, C. L. & Craig, S. L. Molecular engineering of mechanophore activity for stress-responsive polymeric materials. Chem. Sci. 6<\/b>, 2158\u20132165 (2015).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     PubMed Central<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Yao, Y. et al. Remote control of mechanochemical reactions under physiological conditions using biocompatible focused ultrasound. Proc. Natl Acad. Sci. USA 120<\/b>, e2309822120 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     PubMed Central<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Aydonat, S. et al. Leveraging mechanochemistry for sustainable polymer degradation. Polym. J. 56<\/b>, 249\u2013268 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Wang, Z. et al. Toughening hydrogels through force-triggered chemical reactions that lengthen polymer strands. Science 374<\/b>, 193\u2013196 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Wang, S. et al. Facile mechanochemical cycloreversion of polymer cross-linkers enhances tear resistance. Science 380<\/b>, 1248\u20131252 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Sakai, H. et al. Visualization and quantitative evaluation of toughening polymer networks by a sacrificial dynamic cross-linker with mechanochromic properties. ACS Macro Lett. 9<\/b>, 1108\u20131113 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Herzog-Arbeitman, A. et al. Tetrafunctional cyclobutanes tune toughness via network strand continuity. Nat. Chem. 18<\/b>, 309\u2013316 (2026).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Bauer, F. Behavior of ferroelectric ceramics and PVF2 polymers under shock loading. AIP Conf. Proc. 78<\/b>, 251\u2013267 (1982).<\/p>\n

    ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Tang, Z. P. & Gupta, Y. M. Shock-induced phase transformation in cadmium sulfide dispersed in an elastomer. J. Appl. Phys. 64<\/b>, 1827\u20131837 (1988).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Sekine, T. Shock-induced phase transformation of graphite-like boron nitride to denser forms. J. Mater. Sci. Lett. 8<\/b>, 872\u2013874 (1989).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Brown, E. N., Trujillo, C. P., Gray, G. T. III, Rae, P. J. & Bourne, N. K. Soft recovery of polytetrafluoroethylene shocked through the crystalline phase II-III transition. J. Appl. Phys. 101<\/b>, 024916 (2007).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Sun, Y., Kooi, S. E., Nelson, K. A., Hsieh, A. J. & Veysset, D. Impact-induced glass-to-rubber transition of polyurea under high-velocity temperature-controlled microparticle impact. Appl. Phys. Lett. 117<\/b>, 021905 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Hyon, J. et al. Projectile impact shock-induced deformation of one-component polymer nanocomposite thin films. ACS Nano 15<\/b>, 2439\u20132446 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Hyon, J. et al. Extreme energy absorption in glassy polymer thin films by supersonic micro-projectile impact. Mater. Today 21<\/b>, 817\u2013824 (2018).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Lee, J.-H. et al. High strain rate deformation of layered nanocomposites. Nat. Commun. 3<\/b>, 1164 (2012).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Cai, J. & Thevamaran, R. Superior energy dissipation by ultrathin semicrystalline polymer films under supersonic microprojectile impacts. Nano Lett. 20<\/b>, 5632\u20135638 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Veysset, D. et al. High-velocity micro-projectile impact testing. Appl. Phys. Rev. 8<\/b>, 011319\u2013011343 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Xie, W. & Lee, J.-H. Dynamics of entangled networks in ultrafast perforation of polystyrene nanomembranes. Macromolecules 53<\/b>, 1701\u20131705 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Lepage, M. L., Musolino, S. F. & Wulff, J. E. Design, exploitation, and rational improvements of diazirine-based universal polymer crosslinkers. Acc. Chem. Res. 57<\/b>, 3327\u20133342 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Lepage, M. L. et al. A broadly applicable cross-linker for aliphatic polymers containing C\u2013H bonds. Science 366<\/b>, 875\u2013878 (2019).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Klein, I. M., Husic, C. C., Kov\u00e1cs, D. P., Choquette, N. J. & Robb, M. J. Validation of the CoGEF method as a predictive tool for polymer mechanochemistry. J. Am. Chem. Soc. 142<\/b>, 16364\u201316381 (2020).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Wang, S. et al. Mechanism dictates mechanics: a molecular substituent effect in the macroscopic fracture of a covalent polymer network. J. Am. Chem. Soc. 143<\/b>, 3714\u20133718 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Sang, Z. et al. Supersonic puncture-healable and impact resistant covalent adaptive networks. Mater. Today 83<\/b>, 43\u201353 (2025).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Porwal, P. K. & Phoenix, S. L. Effects of layer stacking order on the V50 velocity of a two-layered hybrid armor system. J. Mech. Mater. Struct. 3<\/b>, 627\u2013639 (2008).<\/p>\n

    Article<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Donald, A. M. & Kramer, E. J. Effect of molecular entanglements on craze microstructure in glassy polymers. J. Polym. Sci. Polym. Phys. Ed. 20<\/b>, 899\u2013909 (1982).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Luo, S. M., Barber, R. W., Overholts, A. C. & Robb, M. J. Competitive activation experiments reveal significantly different mechanochemical reactivity of Furan\u2013maleimide and anthracene\u2013maleimide mechanophores. ACS Polym. Au 3<\/b>, 202\u2013208 (2023).<\/p>\n

    Article<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Bowser, B. H. et al. Single-event spectroscopy and unravelling kinetics of covalent domains based on cyclobutane mechanophores. J. Am. Chem. Soc. 143<\/b>, 5269\u20135276 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Centellas, P. J. et al. Mechanochemically responsive polymer enables shockwave visualization. Nat. Commun. 15<\/b>, 8596 (2024).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n     PubMed Central<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Beyer, M. K. The mechanical strength of a covalent bond calculated by density functional theory. J. Chem. Phys. 112<\/b>, 7307\u20137312 (2000).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n

  • \n

    Bowman, A. L., Chan, E. P., Lawrimore, W. B. & Newman, J. K. Supersonic impact response of polymer thin films via large-scale atomistic simulations. Nano Lett. 21<\/b>, 5991\u20135997 (2021).<\/p>\n

    Article<\/a>\u00a0
    \n     ADS<\/a>\u00a0
    \n     CAS<\/a>\u00a0
    \n     PubMed<\/a>\u00a0
    \n
    \n Google Scholar<\/a>\u00a0\n <\/p>\n<\/li>\n","protected":false},"excerpt":{"rendered":"Siviour, C. R. & Jordan, J. L. High strain rate mechanics of polymers: a review. J. Dyn. Behav.…\n","protected":false},"author":3,"featured_media":843121,"comment_status":"","ping_status":"","sticky":false,"template":"","format":"standard","meta":{"footnotes":"","_share_on_mastodon":"0"},"categories":[8],"tags":[10046,167952,10047,155917,159,67,132,68],"class_list":["post-843120","post","type-post","status-publish","format-standard","has-post-thumbnail","category-science","tag-humanities-and-social-sciences","tag-mechanical-properties","tag-multidisciplinary","tag-polymer-synthesis","tag-science","tag-united-states","tag-unitedstates","tag-us"],"share_on_mastodon":{"url":"https:\/\/pubeurope.com\/@us\/116690222137322607","error":""},"_links":{"self":[{"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/posts\/843120","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/comments?post=843120"}],"version-history":[{"count":0,"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/posts\/843120\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/media\/843121"}],"wp:attachment":[{"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/media?parent=843120"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/categories?post=843120"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.europesays.com\/us\/wp-json\/wp\/v2\/tags?post=843120"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}